The full name of pressure sensitive adhesive is pressure sensitive adhesive, also known as self-adhesive, referred to as pressure sensitive adhesive. Pressure-sensitive adhesive products include pressure-sensitive adhesive tape and pressure sensitive adhesive label paper, and pressure-sensitive film in three categories. Their full name is a pressure-sensitive adhesive tape, pressure-sensitive adhesive label paper, pressure-sensitive adhesive sheet, commonly known as adhesive tape, self-adhesive label paper, and pressure-sensitive film.

This component is adjusted to achieve better performance of the product. In order to ensure the good adhesion and peeling strength of pressure-sensitive adhesive in the existing technology, a large number of chemical reagents are often added, which greatly increases the production cost and also produces a large number of toxic chemical raw materials.

smprotectivefilm

As a professional acrylic pressure-sensitive adhesive supplier, Changsheng is committed to solving the problems encountered by customers in the use of glue due to different production equipment and processes.

Compared with traditional solvent-based pressure-sensitive adhesive, our emulsion pressure-sensitive adhesive has the advantages of environmental protection, safety, and easy operation. Using deionized water instead of traditional solvent reduces pollution to the environment and is an ideal environmental protection product.
By adjusting the proportion of the curing agents, pressure-sensitive adhesives with different adhesive forces can be obtained to meet the needs of different applications. Suitable for a variety of materials, transparent after drying.
Our acrylic pressure-sensitive adhesive is widely used in:

1. Fit of different film materials
Hot item: Glue FR-201
Advantages: Our laminating adhesive has strong peeling strength, suitable for laminating BOPP, CPP, PET, PE or other lightweight packaging film materials.

2. Protective film for household appliances
Hot stuff: Glue FR-07; Glue FR-102-2
Advantages: The series of adhesive peeling force increase small, do not leave residue, good anti-scalding performance.
The FR-07 is suitable for smooth surfaces of stainless steel, and the FR-102-2 is suitable for slightly rough surfaces.

3, outdoor protective film
Hot stuff: Glue FR-04; Glue FR-W78-1; Glue FR-091-6
Advantages: This series of glue has the advantages of temperature resistance (including high and low temperature), moisture-proof, and waterproof performance. Their adhesive force is different and can meet different bonding requirements.
Glue FR-091-6 is especially suitable for carpets, fluorocarbon spray aluminum profiles, and other rough surface.

4. Off-line Low-E glass protective film
Hot item: FR-08-J7
Strength: It has the characteristics of strong stripping strength and moderate unwinding performance.
Wuxi Changsheng Adhesive Products Co., Ltd. is also committed to emulsion pressure-sensitive adhesive research and development, production, and sales of the company. We can effectively solve the problems that customers encounter in the use of glue because of different production equipment and technology.

PE-protective-film-for-stainless-sheet

We specialize in the production of the protective film and pressure-sensitive adhesive for many years, with our own R & D team. In the future, through continuous research and development and summing up experience, our glue can be applied to more product application fields.

PET protective film has excellent insulation, strong toughness, heat resistance, cold resistance, and good chemical resistance and oil resistance, widely used in glass steel, electronics, and machinery industries. Because it is an insulator and the surface resistance is large, in the process of production and use, it is easy to generate electrostatic accumulation, leading to dust, electric shock (discharge), spontaneous combustion, and even explosion and other phenomena, which brings inconvenience to industrial production and daily life and even endangers the personal safety of staff.

At present, the protective film industry usually by adding antistatic agents to reduce the surface resistance of the protective film in order to achieve the effect of anti-static. However, the addition of an antistatic agent will affect the temperature resistance of PET protective film, and now the glass fiber-reinforced plastic, electronic and mechanical industries for PET protective film temperature resistance performance requirements are high. Therefore, a PET film with low resistance and good high-temperature resistance is the demand of today’s market. The antistatic agent itself does not have free electrons, belonging to the category of surfactant, it is through ionic or polar groups of ionic conduction or moisture absorption, that forms a leakage charge channel, to achieve the purpose of antistatic.

There are many shortcomings in the use of an external added antistatic agent: first, the addition of an antistatic agent often affects the adhesion, temperature resistance, and other performance of the product, or in the process of use precipitation will pollute the paste; Two, by the passage of time or the use of friction and other factors, the antistatic agent can not be firmly combined in the colloidal surface, easy to lose antistatic properties. To solve the above problems, the technical solution adopted is a pressure-sensitive adhesive for PET protective film, prepared from the following weight of raw materials: Butyl acrylate 20-25 parts, isooctyl acrylate 9-11 parts, acrylic acid 1-3 parts, hydroxyethyl acrylate 2-4 parts, piperidine ethyl methacrylate 1-3 parts, conductive polymer 4-7 parts, initiator 0.15-0.35 parts, solvent 58-62 parts, hardener 2-4 parts.

Changsheng is a wholesale PET protective film manufacturer in China with more than 20 years of experience. In addition to PE protective film, we also provide PET protective film to protect the PVC profile of the window. PVC profiles are also faced with many possibilities of damage in the process of production, transportation, and installation. It also requires the same surface protection throughout the process to avoid dust, scratches, erosion, and damage.

pressure sensitive adhesive

Polyester (PET) film is a type of plastic widely used in many applications. PET material has good chemical resistance, is tough, and is durable. Our PVC profile protective film is two layers of pressure protective film. One layer contains an aluminum layer that blocks light and moisture and protects against ultraviolet radiation. It can help PVC profiles to achieve anti-fading or anti-aging protection to a certain extent. At the same time, the emulsion pressure-sensitive adhesive we use for coating has temperature resistance and is suitable for outdoor use. Therefore, our PET protective film has excellent high and low-temperature performance, UV resistance, waterproof performance, and high puncture performance. According to customer feedback, its aging performance is indeed better than other protective film products.

In addition to excellent weather resistance, our PET protective film provides surface protection for PVC profiles against dust, scratching, or damage. Its glossy appearance, logo, and specifications can be customized to meet your requirements.

On the market, there are many flame-retardant pressure-sensitive adhesives made of halogenated flame retardants that are harmful to the environment.

Pressure-sensitive adhesive is a kind of adhesive without the aid of a solvent, heat, or other means, just applies mild pressure, and can be firmly bonded with the adhesive. Its characteristics are easy to stick, uncovered is not difficult, and it a long time the adhesive layer will not dry solid, so the pressure-sensitive adhesive is also called self-adhesive. It is because of this property of pressure-sensitive adhesive, that its products are widely used in packaging, printing, medical, home appliances, and manufacturing industries.

Hot melt pressure sensitive adhesive

There are many kinds of pressure-sensitive adhesives. According to different classification standards, pressure-sensitive adhesives can be divided into various types. The common classification is according to the composition of the main material of pressure sensitive adhesive is divided into rubber series and resin series two categories, further can be divided into rubber pressure sensitive adhesive, thermoplastic elastomer pressure sensitive adhesive, acrylic ester pressure sensitive adhesive, silicone pressure sensitive adhesive and polyurethane pressure sensitive adhesive. Among them, acrylate pressure-sensitive adhesive is the hot research and development at present.

Acrylate pressure-sensitive adhesives are formed by the copolymerization of acrylate monomers and other vinyl monomers. The acrylic pressure-sensitive adhesive formula is simple, wide bonding range, good weather resistance, light resistance, excellent oil resistance, good water resistance, and no phase separation, and migration phenomenon, so it is widely used in various fields.

But now many industries need to have the flame retardant performance of pressure-sensitive adhesive, especially now electronic products battery requires strong acid and alkali resistance and flame retardant performance, and ordinary acrylic acid pressure sensitive adhesive does not have strong acid and alkali resistance and flame retardant performance, in addition to the market there are many flame retardant pressure sensitive adhesive made with halogen flame retardant agent, combustion will release toxic hydrogen halide gas, harmful to the environment and human body. Therefore, we need to provide a pressure-sensitive adhesive with strong acid and alkali resistance and flame retardant, which not only can resist strong acid and alkali but also does not have flame retardant properties.

It is necessary to invent a pressure sensitive adhesive for life test dosage

As a kind of adhesive material, tape has its special application, such as fixed bonding of materials, surface protection, and soon. With the faster and faster upgrading of the electronic industry, the requirements for electronic adhesive tape are becoming higher and higher. More electronic applications have put forward the requirements for adhesive tape to withstand the living substances in contact with life, such as laundry detergent, sweat, alcohol, food grease, etc., which are exactly the majority of ordinary adhesive tape can not tolerate.

a pressure sensitive adhesive

It has been reported that a rubber belt company developed a kind of pressure sensitive rubber belt with good resistance to living reagents using nitrile rubber, but there are some problems such as low bond strength, poor ozone resistance, poor insulation performance, and low resilience. It has also been reported that the graft of acrylonitrile-butadiene styrene (ABS) with methacrylate can improve the impact resistance and life resistance of the material, but for electronic adhesive belts said that these ABS materials can not be applied to pressure sensitive adhesive products. Nowadays, how to improve the resistance of electronic adhesives to living reagents has been reported more and more.

At present, most of the tape on the market in addition to providing bonding properties is not resistant to life reagents in life. In recent years, a rubber belt company has developed a kind of double-sided rubber belt with resistance to the living reagents. The main material is an acrylonitrile-butadiene elastomer, which has excellent resistance to living reagents. However, the system products have some problems, such as hard hardness, low elasticity, low-temperature resistance, and ozone resistance. Therefore, it is necessary to seek a pressure sensitive adhesive and adhesive tape with high bond strength, good resistance to living reagents, good aging resistance, and suitable for the wide temperature range of applications. Therefore, it is necessary to invent a preparation method of pressure sensitive adhesive composition and its adhesive tape.

Acrylic pressure sensitive adhesive

Acrylic polymer-like compositions have long been used as adhesive compositions, particularly in pressure-sensitive adhesive (” PSA “) compositions. They exhibit adhesion to a wide variety of surfaces, display good low-temperature properties, often produce attractive transparent adhesives, and possess excellent thermal, aging, and UV stability. Acrylic binder polymers can be obtained as organic (solvent) solutions, aqueous emulsions, and 100% solid thermoplastic systems applied as melts. Initially, the most common PSA is solvent acrylic, but market demand leads to the rapid growth of water-based acrylic, also known as emulsion acrylic adhesives. Traditionally, acrylic PSA compositions are characterized by the selection of acrylic monomers and polymerization conditions. Examples of such properties are cohesion (such as shear strength) and adhesion (such as adhesion and peel strength).

Acrylic pressure sensitive adhesive

For example, acrylate monomers that reduce the glass transition temperature of acrylic polymers (e.g., butyl acrylate and 2-ethylhexyl acrylate) improve adhesion properties, while acrylate monomers and vinyl monomers that raise the glass transition temperature of acrylic polymers improve cohesion properties (e.g., methyl methacrylate, styrene, and vinyl acetate). Unfortunately, more use of one monomer leads to less of the other, so cohesion and adhesion are often inversely correlated, so an improvement in one property causes a decline in the other.

Usually, we use pure monomer synthesis emulsion acrylic PSA. Acrylate monomers that give adhesion properties usually include straight carbon chains (e.g., butyl acrylate) or single-branched carbon chains (e.g., (methyl) acrylate monomers of 2-ethylhexyl acrylate and C12-C322-alkyl alkanols). However, it is also possible to use mixtures of (methyl) acrylate alkyl monomers with carbon chains (or carbon numbers) of varying lengths and different branched carbon chains including two or more branches. Unconstrained by theory, it is believed that the diversification of carbon chain length and increased branching improves the cohesive properties of acrylic Psas (including, for example, more than a five-fold improvement in shear strength) while maintaining the adhesive properties of acrylic Psas.

UV degumming pressure sensitive adhesive for porous substrates

Porous ceramic materials including anodized alumina are increasingly used in appearance parts in the consumer electronics industry. In the process of processing porous materials, it is necessary to use protective film such as tape for temporary protection. The surface of anodized alumina used in the back shell of mobile phones has a large number of nanoscale pores. The adhesive force of the typical protective film tape on the porous surface is very poor, and it is easy to fall off when the back cover is processed by computer numerical control (CNC), which does not provide adequate protection.

And the high viscosity of the protective film, the adhesive layer is easy to penetrate the microhole, when the removal of the protective film will form residual glue, and the removal force is large, the need for an additional cleaning process. Pressure sensitive adhesives that can be UV – bonded have been used for protective film tape. UV photodesinking pressure sensitive adhesive is also known as UV drinking adhesive, which refers to a class of pressure sensitive adhesives that can reduce the adhesion through UV photoexcitation. UV viscose has the characteristics of easy construction, high initial adhesion, and easy removal after UV viscose.

UV degumming pressure sensitive adhesive

Existing UV adhesives typically consist of pressure sensitive adhesives, UV-polymerizable oligomers (also known as UV oligomers, or adhesives), and free radical-type photoinitiators. Pressure sensitive adhesive provides initial bonding. When UV light is irradiated, UV oligomers crosslinking under the action of free radical photoinitiator makes the overall modulus of the de viscose adhesive improve. In this way, the adhesive layer hardens and loses its adhesion. UV adhesive as a protective film tape has a good initial adhesive relay, and in CNC processing will not fall off.

After processing, the adhesive tape is reduced by UV light, which can be easily removed. However, due to the limitation of their adhesive formulation, the unglued UV oligomers migrate into micropores when applied to porous surfaces. UV unglued, glue will further remain on the surface, difficult to remove clean. When color particles are added to the pores by subsequent nano-injection molding techniques to improve the appearance of anodic alumina, the appearance of anodic alumina will be seriously affected by residual de viscose adhesives, especially those migrating into micropores.

Body pressure sensitive adhesive film

Pressure sensitive adhesive coating of the body is attached to the surface of the car paint by polymeric materials, so as to protect the original paint and decorate the body. It can be easily removed at any time, which is in sharp contrast to the chemical changes of the traditional glaze, coating, spray painting, and other paint surfaces. The auto-body coating is a high-performance and low-viscosity PVC film designed for auto-body coating. It has the properties of fully fitting the paint and interior surfaces of various substrates and has many advantages such as more convenient construction, flexibility, durability, chemical corrosion resistance, light permeability, and so on.

It can effectively ensure accurate, seamless, and bubble-free coating when facing the tortuous body surface in the construction process. It will not cause damage to the car paint. On the contrary, it will fully protect the original paint of the vehicle. At present, the car coating substrate is used in the market as long as there are PVC and PU two materials. PVC material car clothing film because of its cheap price, ease to use, in the mainstream position in the market, but because there are a lot of plasticizers in PVC substrate, after aging, migration to the pressure sensitive adhesive film, resulting in a sharp reduction of adhesive cohesion-layer, in the stripping of residual glue.

energy vehicles

Plasticizers added to PVC can reduce the intermolecular chain force so that the glass transition temperature of PVC plastic, flow temperature, and the melting point of the microcrystals are reduced, plasticizer can improve the plasticity of resin, soft products, low-temperature resistance performance.

As long as there are plasticizers currently used in PVC, fatty acid esters, such as dioctyl adipate (DOA): Diiso-decyl metal hydrate (DIDA), dioctyl azelaic acid (D0Z), dioctyl sebacate (DBS), dioctyl sebacate (DOS), disco-octyl sebacate (DIOS), di-(2-methyl butyric acid) trimethylene glycol ester (3GH); Phthalates, such as dioctyl phthalate (DOP), disco-octyl phthalate (DIOP), disco-decyl phthalate (DIDP), disco-nonyl phthalate (DINP), dibutyl phthalate (DBP), diisobutyl phthalate (DIBP), butyl benzyl phthalate (BBP), Dimethyl phthalate (DMP), diethyl phthalate (DEP), dicyclohexyl phthalate (DCHP), dioctyl terephthalate (DOTP) pressure sensitive adhesive is used in various fields of daily life, different fields have different requirements for pressure sensitive adhesive.

In the field of automotive automotive clothing, the pressure sensitive adhesive requirements have excellent aging resistance, and can not produce residual glue when stripping. With appropriate peeling force, when the construction of the film, if you find that the paste is not correct, you can timely, easy to tear off the heavy paste, paste, in the bending surface, and the corner is not easy to tilt the head.

Application of pressure sensitive adhesive in hot compress therapy

Hot compress therapy is the practice of placing a hot object such as a hot water bag or a hot towel over a sore area to eliminate or reduce pain. This is an ancient form of hot compress therapy. The indications of hot compress therapy are very wide, for BI syndrome, such as rheumatoid arthritis caused by pain; Hit injury, especially soft tissue injury; Digestive diseases, such as stomach pain, bloating, adhesive ileus, flatulence, and women dysmenorrhea, mastitis, and other diseases have a better curative effect. Because this method is simple and effective, it has not only been used since ancient times but has also become one of the commonly used therapies for self-prevention and treatment in People’s Daily life.

There are two commonly used hot compress methods, one is the use of open water bag hot compress, open water bag hot compress has the advantages of convenient use and low cost, but there are problems such as fast heat dissipation, short hot compress time, hot compress effect is poor, now the more popular electric hot compress bag, can continue to heat, hot compress effect is good, but the cost is high, must be connected to electricity, use is limited, In addition, electric heating consumes electric energy and involves a series of problems such as electrical safety.

The other is the current patent prefers the use of kosher salt hot compress, but although kosher salt hot compress does not use electricity, because the specific volume of salt is much lower than water and does not have the function of heating for a long time, so it is very inconvenient to use.

pressure sensitive adhesive

Finally, neither of the existing technologies has self-adhesion, spontaneous heat, or any therapeutic effect other than physical therapy. To sum up, in order to popularize hot compress therapy better, there must be a hot compress product that can overcome the above problems. The hot compress in the existing technology is limited by the lack of technical field and practical experience. At present, there is still no hot compress in the market with good pressure sensitive adhesive, good skin affinity, self-heating, green environmental protection, non-pollution, obvious acupuncture treatment effect, adapt to industrial mass production, self-adhesion, with drug treatment effect and probiotic microbial health effect.

Therefore, there is an urgent need in the market for a hot compress with good pressure sensitive adhesive, good skin affinity, self-generated heat, green environmental protection, and non-pollution, obvious acupuncture treatment effect, adapt to industrial mass production, self-adhesion, with drug treatment effect and probiotic microbial health effect.

Improve the antistatic property of pressure sensitive adhesive

With the rapid development of electronic science and technology, microelectronics are becoming more and more sophisticated, and the damage caused by static electricity to electronic equipment such as touch screens, chips, and large-scale integrated circuits is more and more serious. Silicone pressure sensitive adhesive has good chemical resistance, weather resistance, heat resistance, and a wide range of use, is a good silicone pressure sensitive adhesive material that can be prepared with an antistatic effect. Using the antistatic protective film prepared by it, it is easy to derive the static electricity generated in the process of electronic materials, so as to avoid the damage of electronic materials caused by electrostatic accumulation.

How to prepare a silicone pressure sensitive adhesive with a good antistatic effect is still an urgent problem to be solved at present. In order to solve the above technical problems, the following technical solutions are provided. A method of preparation of antistatic silicone pressure sensitive adhesive, including the following steps:

step 1: take the multi-walled carbon nanotubes, modified ionic liquid, grinding 50  60 min, to join the deionized water, ultrasonic dispersion 90  120 min, by adsorption of an ionic liquid suspension of carbon nanotubes, in 65  drying under 70 ℃, carbon nanotubes by adsorption of ionic liquid;

Step two: Organic silicon resin PSA1057, ethyl acetate, crosslinking agent, a platinum catalyst, hydrogen silicone under a speed of 4500 r/min 3500  star 1  2 h, add heat resistant filler, adsorption of ionic liquid carbon nanotubes, under a speed of 6000 r/min 5000  star 3  4 h, let stand deaeration, An antistatic silicone pressure sensitive adhesive was obtained.

pressure sensitive adhesive

Compared with the existing technology, the invention has the beneficial effects of

(1) this application USES 1  butyl imidazole, 3  bromine propionic acid, preparation of ionic liquid, and then adds in the six fluorides, potassium phosphate, through ion exchange preparation of carboxyl ionic liquids, the carboxyl ionic liquid, chemical stability, good solubility, added to the pressure sensitive adhesive, can make it has good antistatic performance. After the hydroxylation of talc powder, the hydroxyl group on talc powder will undergo an esterification reaction with the carboxyl group on the carboxyl ionic liquid, and then graft together, which can improve the dispersion of talc in the pressure sensitive adhesive.

Meanwhile, the hydroxyl group on talc can improve the molecular polarity of organosilicon resin, improve the adhesion force of organosilicon pressure sensitive adhesive, and improve the peeling force of pressure sensitive adhesive.

(2) Ionic liquid is a substance composed of anions and ions, which can improve the antistatic performance of pressure sensitive adhesive, but the stability is not good in pressure sensitive adhesive. Multi-walled carbon nanotubes and mechanical performance are good, good electrical conductivity, but easy to reunite, modified ionic liquid adsorbed on multi-walled carbon nanotubes, solved the multi-walled carbon nanotubes not easily dispersed in the psa, control of multi-walled carbon nanotubes, modified ionic liquid mass ratio of (0. 1  0. 2): At this time, to add a large amount of multi-walled carbon nanotubes, carbon nanotubes can lap together to form a conductive path, to reduce the resistivity, improve the antistatic property of pressure sensitive adhesive.

The emulsifier determines whether the acrylic pressure sensitive adhesive can form a stable and uniform adhesive system

Pressure sensitive adhesive is a kind of pressure sensitive adhesive, that does not need to add other additives or heating, only needs to apply a small pressure can be firmly bonded with the substrate, after the unveiling will not have a shadow on the surface of the substrate, its characteristics are easy to stick, uncovered is not difficult, stripping without damage, in a long time the adhesive layer will not dry up, Therefore, pressure sensitive adhesive is also called self-adhesive. Pressure-sensitive adhesive products are used in packaging, automobile, transportation, communication, electrical appliances, building materials, machinery, aviation, light industry, health, and other fields. Because of its convenient use, easy operation, and wide range of applications, pressure-sensitive adhesive has developed rapidly.

Emulsifier is to determine whether the acrylate adhesive can form a stable and uniform adhesive system, which determines the quality of the acrylic emulsion polymerization process, an emulsifier can disperse monomer into a storage monomer as the center of the fine monomer droplets, and the formation of the emulsion can also form micelles and sol-increasing beam, according to the micellar mechanism as the formation of the reaction center of the latex particle. It can be adsorbed on the surface of monomer droplets and latex particles to form a stable polymer emulsion, which will not break milk in the process of polymerization, storage, transportation, and application. At the same time, the emulsifier also directly affects the polymerization rate of the emulsion.

acrylic pressure sensitive adhesive

Therefore, whether emulsion polymerization can be successfully carried out and whether polymer emulsion and emulsion polymer with excellent properties can be made, the correct selection and rational use of emulsifier can not be ignored. Another important parameter of the emulsifier is the hydrophilic and oil-philic balance value, that is, the HLB value, which is used to measure the hydrophilicity and oil publicity of the emulsifier. The larger the HLB value is, the greater the hydrophilicity of the emulsifier will be. Each emulsifier has a specific HLB value, generally in the range of 1 to 40. HLB value is an important basis for selecting an emulsifier.

Initiator is an important component of the acrylate emulsion polymerization formula, the type and amount of initiator are directly related to the polymerization reaction rate, the stability of polymer emulsion, and the quality of the product, so the correct selection of initiator is also a very important issue for emulsion polymerization formula design.